We report on a comparison between the random disorder effects of an hydrophobic (R812) or an hydrophilic (A380) aerosil on the order and dynamics of the 3beta-DOXYL-5alpha-cholestane spin probe in the liquid crystal 4-n-pentyl-4'-cyanobiphenyl (5CB) using the ESR technique. Increasing the aerosil concentration up to 3 wt% the probe order parameter is depressed with a larger effect for the hydrophilic aerosil. The dynamics in the isotropic phase is of Arrhenius type and essentially concentration and aerosil-type independent. Deviations from this behavior are observed in the nematic even at 0.3 wt% of hydrophilic aerosil and are well represented by a Vogel-Fulcher-Tammann type law, suggesting that a glass-like state can be induced by a very small amount of random disorder.

A comparison of the effects of dispersed hydrophobic or hydrophilic aerosil nanoparticles on the order and dynamics of the 5CB liquid crystal

BACCHIOCCHI, CORRADO;
2004-01-01

Abstract

We report on a comparison between the random disorder effects of an hydrophobic (R812) or an hydrophilic (A380) aerosil on the order and dynamics of the 3beta-DOXYL-5alpha-cholestane spin probe in the liquid crystal 4-n-pentyl-4'-cyanobiphenyl (5CB) using the ESR technique. Increasing the aerosil concentration up to 3 wt% the probe order parameter is depressed with a larger effect for the hydrophilic aerosil. The dynamics in the isotropic phase is of Arrhenius type and essentially concentration and aerosil-type independent. Deviations from this behavior are observed in the nematic even at 0.3 wt% of hydrophilic aerosil and are well represented by a Vogel-Fulcher-Tammann type law, suggesting that a glass-like state can be induced by a very small amount of random disorder.
2004
262
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/201412
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