In response to growing concerns about the greenhouse effect, the direct conversion of atmospheric CO2 has become a pivotal research focus. This research utilizes hydrothermal synthesis to develop Bi2WO6/MXene(Ti3C2Tx), which efficiently reduces CO2 directly at the gas–solid interface through photothermal synergy, without requiring additional sacrificial agents or alkaline absorption solutions. The results indicate that the CO formation rate is about 216.9 μmol·g−1h−1. Notably, this system demonstrates exceptional selectivity for reducing CO2 to CO. The outstanding photothermal catalytic efficiency is attributed to the introduction of MXene, which serves as an efficient and economical co-catalyst. The integration of MXene improves the composite material’s specific surface area and pore structure, enhances its CO2 adsorption capacity, and results in the Bi2WO6/MXene hybrid having a shorter charge transfer distance and a larger interface contact area. This ensures superior charge transfer capabilities, ultimately leading to a significant enhancement in the catalytic efficiency of the composite. This study presents a straightforward and highly selective method for capturing and converting atmospheric CO2, offering fresh insights for developing efficient photothermal catalytic materials.

Preparation of Bi2WO6/MXene(Ti3C2Tx) Composite Material and Its Photothermal Catalytic Reduction of CO2 in Air

Meng, Yang;Li, Cong;Berrettoni, Mario;Zamponi, Silvia;
2024-01-01

Abstract

In response to growing concerns about the greenhouse effect, the direct conversion of atmospheric CO2 has become a pivotal research focus. This research utilizes hydrothermal synthesis to develop Bi2WO6/MXene(Ti3C2Tx), which efficiently reduces CO2 directly at the gas–solid interface through photothermal synergy, without requiring additional sacrificial agents or alkaline absorption solutions. The results indicate that the CO formation rate is about 216.9 μmol·g−1h−1. Notably, this system demonstrates exceptional selectivity for reducing CO2 to CO. The outstanding photothermal catalytic efficiency is attributed to the introduction of MXene, which serves as an efficient and economical co-catalyst. The integration of MXene improves the composite material’s specific surface area and pore structure, enhances its CO2 adsorption capacity, and results in the Bi2WO6/MXene hybrid having a shorter charge transfer distance and a larger interface contact area. This ensures superior charge transfer capabilities, ultimately leading to a significant enhancement in the catalytic efficiency of the composite. This study presents a straightforward and highly selective method for capturing and converting atmospheric CO2, offering fresh insights for developing efficient photothermal catalytic materials.
2024
atmospheric CO
2
capture
Bi
2
WO
6
/MXene
CO
2
reduction
gas–solid interface
photothermal catalytic
262
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/500245
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