A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shell
Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures
Giorgetti Marco;Berrettoni Mario
2015-01-01
Abstract
A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by highresolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co–N first shellFile in questo prodotto:
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