A combined experimental and computational investigation of the photoreactivity of (E)-β-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-β-nitroenones and deconjugation to β-nitro-β,γ-enones. Both processes are generated from the triplet excited state of the starting substrates.
Visible-Light-Driven Competitive Stereo- and Regioisomerization of (E)-β-Nitroenones
Alessandro Palmieri;Gabriele Lupidi;
2021-01-01
Abstract
A combined experimental and computational investigation of the photoreactivity of (E)-β-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-β-nitroenones and deconjugation to β-nitro-β,γ-enones. Both processes are generated from the triplet excited state of the starting substrates.File in questo prodotto:
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