A combined experimental and computational investigation of the photoreactivity of (E)-β-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-β-nitroenones and deconjugation to β-nitro-β,γ-enones. Both processes are generated from the triplet excited state of the starting substrates.

Visible-Light-Driven Competitive Stereo- and Regioisomerization of (E)-β-Nitroenones

Alessandro Palmieri;Gabriele Lupidi;
2021-01-01

Abstract

A combined experimental and computational investigation of the photoreactivity of (E)-β-nitroenones pointed out the occurrence of competitive pathways namely stereoisomerisation to (E)-β-nitroenones and deconjugation to β-nitro-β,γ-enones. Both processes are generated from the triplet excited state of the starting substrates.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/457423
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 8
  • ???jsp.display-item.citation.isi??? 7
social impact