The Hg(II) complex [Hg(TFP)2(OTFP)3][ClO4]2 with TFP = tri-2-furyl-phosphine and OTFP = tri-2-furylphosphinoxide has been prepared and characterized. It crystallizes in the hexagonal P63/m space group with Z=2, a=13.308(3), c=21.092 (4) Å , V=3235(1) Å3. The structure of the complex cation consists of independent molecules with Hg pentacoordinated in exact trigonal bipyramidal geometry.
Crystal structure of a novel Hg(II) complex, [Hg(tri-2-furylphosphine)2(tri-2-furylphosphinoxide)3][ClO4]2
BURINI, Alfredo;GALASSI, Rossana;
2005-01-01
Abstract
The Hg(II) complex [Hg(TFP)2(OTFP)3][ClO4]2 with TFP = tri-2-furyl-phosphine and OTFP = tri-2-furylphosphinoxide has been prepared and characterized. It crystallizes in the hexagonal P63/m space group with Z=2, a=13.308(3), c=21.092 (4) Å , V=3235(1) Å3. The structure of the complex cation consists of independent molecules with Hg pentacoordinated in exact trigonal bipyramidal geometry.File in questo prodotto:
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