Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.
Organosilicon linkers in metal organic frameworks: The tetrahedral tetrakis(4-tetrazolylphenyl)silane ligand
TIMOKHIN, IVAN;PETTINARI, Claudio;
2014-01-01
Abstract
Formal substitution of the central carbon by silicon within the tetrahedral tetrakis(4-tetrazolylphenyl)methane linker in a copper-based MOF is shown to uniquely influence the structure of the resultant MOF, affecting the orientation of the metal-based nodes and leading to an increase in unit-cell volume and solvent accessible void space.File in questo prodotto:
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