The reaction of ylidene malononitriles with b-nitroacrylates, in Et3N/MeCN, affords the one-pot synthesis of a new class of penta-substituted, densely functionalized anilines in satisfactory to good overall yields. The method represents a very important improvement of the recent strategy for the preparation of anilines from conjugated nitroalkenes.

beta-Nitroacrylates as key starting materials for the one-pot synthesis of densely functionalized penta-substituted anilines

GABRIELLI, Serena;PALMIERI, Alessandro;BALLINI, Roberto
2012

Abstract

The reaction of ylidene malononitriles with b-nitroacrylates, in Et3N/MeCN, affords the one-pot synthesis of a new class of penta-substituted, densely functionalized anilines in satisfactory to good overall yields. The method represents a very important improvement of the recent strategy for the preparation of anilines from conjugated nitroalkenes.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11581/250209
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