The reaction of ylidene malononitriles with b-nitroacrylates, in Et3N/MeCN, affords the one-pot synthesis of a new class of penta-substituted, densely functionalized anilines in satisfactory to good overall yields. The method represents a very important improvement of the recent strategy for the preparation of anilines from conjugated nitroalkenes.
beta-Nitroacrylates as key starting materials for the one-pot synthesis of densely functionalized penta-substituted anilines
GABRIELLI, Serena;PALMIERI, Alessandro;BALLINI, Roberto
2012-01-01
Abstract
The reaction of ylidene malononitriles with b-nitroacrylates, in Et3N/MeCN, affords the one-pot synthesis of a new class of penta-substituted, densely functionalized anilines in satisfactory to good overall yields. The method represents a very important improvement of the recent strategy for the preparation of anilines from conjugated nitroalkenes.File in questo prodotto:
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