It has been found that commercial ISOLUTE(R)Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and gamma-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.
Isolute(R)Si-Carbonate catalyzes the nitronate addition to both aldehydes and electron-poor alkenes under solvent-free conditions
BALLINI, Roberto;BOSICA, Giovanna;PALMIERI, Alessandro;
2008-01-01
Abstract
It has been found that commercial ISOLUTE(R)Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and gamma-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.File in questo prodotto:
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