Treatment of secondary nitroalkanes with neat silica-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), at room temperature, allows the direct conversion of the secondary nitro groups to the corresponding keto carbonyls.
SiO2-TBD as New Heterogeneous Catalyst for the Nef Conversion of Secondary Nitroalkanes under Neat Conditions
BALLINI, Roberto;FIORINI, Dennis;PALMIERI, Alessandro;
2006-01-01
Abstract
Treatment of secondary nitroalkanes with neat silica-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), at room temperature, allows the direct conversion of the secondary nitro groups to the corresponding keto carbonyls.File in questo prodotto:
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