(Z)-1-Nitro-3-hexene is a versatile reagent corresponding to the (Z)-3-hexen-1-yl d1-synthon. Nitroaldol addition, oxidation and denitration are the steps of a new methodology to conveniently prepare the title compounds, which are popular intermediates in the synthesis of (Z)-jasmololone and (Z)-jasmone.

(Z)-1-Nitro-3-hexene as Reagent for (Z)-Hexen-1-yl Anion Synthon: Synthesis of (Z)-5-Octen-2-one and (Z)-1,Undecadien-5-one

BALLINI, Roberto;PETRINI, Marino;
1986

Abstract

(Z)-1-Nitro-3-hexene is a versatile reagent corresponding to the (Z)-3-hexen-1-yl d1-synthon. Nitroaldol addition, oxidation and denitration are the steps of a new methodology to conveniently prepare the title compounds, which are popular intermediates in the synthesis of (Z)-jasmololone and (Z)-jasmone.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11581/241434
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