(±)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicyclo¦3.2.0¦heptane-3-one and its oxime by an improved procedure. 2,5,5-Trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes. Its conversion into ( )grandisol was performed emploing the photobicyclization as key step.
StereoselectiveTotal Synthesis of Racemic Grandisol via 3-Oximino-1,4,4-Trimethyl bicyclo (3.2.0)-Heptane. An Improved Practical Procedure
PETRINI, Marino;BALLINI, Roberto
1986-01-01
Abstract
(±)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicyclo¦3.2.0¦heptane-3-one and its oxime by an improved procedure. 2,5,5-Trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes. Its conversion into ( )grandisol was performed emploing the photobicyclization as key step.File in questo prodotto:
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