(±)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicyclo¦3.2.0¦heptane-3-one and its oxime by an improved procedure. 2,5,5-Trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes. Its conversion into ( )grandisol was performed emploing the photobicyclization as key step.

StereoselectiveTotal Synthesis of Racemic Grandisol via 3-Oximino-1,4,4-Trimethyl bicyclo (3.2.0)-Heptane. An Improved Practical Procedure

PETRINI, Marino;BALLINI, Roberto
1986-01-01

Abstract

(±)Grandisol was stereoselectively obtained via 1,4,4-trimethylbicyclo¦3.2.0¦heptane-3-one and its oxime by an improved procedure. 2,5,5-Trimethylhept-1,6-dien-4-ol, the open chain molecule, was synthesized by two routes. Its conversion into ( )grandisol was performed emploing the photobicyclization as key step.
1986
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/241431
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