ω-Nitroalcohols have been prepared by a new and efficient chemio- and regioselective reductive cleavage performed on 2-nitrocycloketones with sodium borohydride in acetonitrile / water. This reaction opens a more practical and convenient route to the synthesis of spiroketals.
New and Efficient Synthesis of ω-Nitro Alcohols and Spiroketals by Chemio- and Regioselective Reductive Cleavage of 2-Nitrocyclo Alkanones
BALLINI, Roberto;PETRINI, Marino;
1990-01-01
Abstract
ω-Nitroalcohols have been prepared by a new and efficient chemio- and regioselective reductive cleavage performed on 2-nitrocycloketones with sodium borohydride in acetonitrile / water. This reaction opens a more practical and convenient route to the synthesis of spiroketals.File in questo prodotto:
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