Reaction of optically active nitroalkanes with Grignard reagents affords E-Z mixtures of nitrones which can be reduced to chiral hydroxylamines and amines.
Enantoselective Synthesis of Nitrogen Derivatives by Allyl Grignard Addition on Optically Active Nitroalkanes
BARTOLI, Giuseppe;MARCANTONI, Enrico;PETRINI, Marino
1991-01-01
Abstract
Reaction of optically active nitroalkanes with Grignard reagents affords E-Z mixtures of nitrones which can be reduced to chiral hydroxylamines and amines.File in questo prodotto:
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