New copper(l) complexes have been synthesized from the reaction of CuCl with 4- or 2-(diphenylphosphane)benzoic acid and KH2B(btz)(2), KHB(btz)(3), NaTp(Mc), KpzTp, KpzTp(Me) and KH2B(im)(2)(dmac). The complexes obtained have been characterized by elemental analyses and FT-IR in the solid state, and by NMR (H-1 and P-31{H-1}) and electrospray mass spectroscopy in solution. Chemiluminescence technique was used to evaluate the superoxide scavenging activity of these new copper complexes.

New (diphenylphosphane)benzoic acid copper(I) derivatives of “scorpionate” ligands with superoxide scavenging activity

SANTINI, Carlo;PELLEI, Maura;
2004-01-01

Abstract

New copper(l) complexes have been synthesized from the reaction of CuCl with 4- or 2-(diphenylphosphane)benzoic acid and KH2B(btz)(2), KHB(btz)(3), NaTp(Mc), KpzTp, KpzTp(Me) and KH2B(im)(2)(dmac). The complexes obtained have been characterized by elemental analyses and FT-IR in the solid state, and by NMR (H-1 and P-31{H-1}) and electrospray mass spectroscopy in solution. Chemiluminescence technique was used to evaluate the superoxide scavenging activity of these new copper complexes.
2004
262
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/208704
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 21
social impact