New copper(l) complexes have been synthesized from the reaction of CuCl with 4- or 2-(diphenylphosphane)benzoic acid and KH2B(btz)(2), KHB(btz)(3), NaTp(Mc), KpzTp, KpzTp(Me) and KH2B(im)(2)(dmac). The complexes obtained have been characterized by elemental analyses and FT-IR in the solid state, and by NMR (H-1 and P-31{H-1}) and electrospray mass spectroscopy in solution. Chemiluminescence technique was used to evaluate the superoxide scavenging activity of these new copper complexes.
Scheda prodotto non validato
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo
Titolo: | New (diphenylphosphane)benzoic acid copper(I) derivatives of “scorpionate” ligands with superoxide scavenging activity |
Autori: | |
Data di pubblicazione: | 2004 |
Rivista: | |
Abstract: | New copper(l) complexes have been synthesized from the reaction of CuCl with 4- or 2-(diphenylphosphane)benzoic acid and KH2B(btz)(2), KHB(btz)(3), NaTp(Mc), KpzTp, KpzTp(Me) and KH2B(im)(2)(dmac). The complexes obtained have been characterized by elemental analyses and FT-IR in the solid state, and by NMR (H-1 and P-31{H-1}) and electrospray mass spectroscopy in solution. Chemiluminescence technique was used to evaluate the superoxide scavenging activity of these new copper complexes. |
Handle: | http://hdl.handle.net/11581/208704 |
Appare nelle tipologie: | Articolo |
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.