The Au(I) complex [Au(tfp)Cl] with tfp = (C4H3O)3P has been prepared and characterised. It crystallises in the monoclinic P21/n space group with z = 4, a = 9.837(3), b = 12.684(4), c = 11.103(5)A° , β = 91.58(2)◦ and V = 1384.8(2)°A3. The structure of the complex consists of molecules connected in head-to-tail dimers by a metal-halogen contact as generally found in analogus complexes of lighter coinage metals. The typical feature of halogen gold compounds, the Au Au interaction, seems prevented by the bulk of the tfp ligand.

Crystal structure of the gold(I) complex [Au(tfp)Cl] with tfp =(C4H3O)(3)P

BURINI, Alfredo;GALASSI, Rossana;
2004-01-01

Abstract

The Au(I) complex [Au(tfp)Cl] with tfp = (C4H3O)3P has been prepared and characterised. It crystallises in the monoclinic P21/n space group with z = 4, a = 9.837(3), b = 12.684(4), c = 11.103(5)A° , β = 91.58(2)◦ and V = 1384.8(2)°A3. The structure of the complex consists of molecules connected in head-to-tail dimers by a metal-halogen contact as generally found in analogus complexes of lighter coinage metals. The typical feature of halogen gold compounds, the Au Au interaction, seems prevented by the bulk of the tfp ligand.
2004
262
File in questo prodotto:
File Dimensione Formato  
JCC 2004.pdf

solo gestori di archivio

Descrizione: Galassi
Tipologia: Versione Editoriale
Licenza: NON PUBBLICO - Accesso privato/ristretto
Dimensione 191.21 kB
Formato Adobe PDF
191.21 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/203112
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 4
  • ???jsp.display-item.citation.isi??? 4
social impact