The chemoselective S(N)2' reaction of a variety of primary nitroalkanes to dialkyl 2-(bromomethyl)fumarates can be efficiently performed under cetyltrimethylammonium hydroxide (CTAOH) catalysis. The alpha, beta-unsaturated esters were obtained in satisfactory to good yields with the complete retention of the nitro group. (C) 2009 Elsevier Ltd. All rights reserved.
Chemoselettive SN2’ Reaction of Nitroalkanes to Dialkyl 2-(Bromomethyl)fumarates under Cetyltrimethylammonium hydroxide (CTAOH) Catalysis
BALLINI, Roberto;GABRIELLI, Serena;PALMIERI, Alessandro
2010-01-01
Abstract
The chemoselective S(N)2' reaction of a variety of primary nitroalkanes to dialkyl 2-(bromomethyl)fumarates can be efficiently performed under cetyltrimethylammonium hydroxide (CTAOH) catalysis. The alpha, beta-unsaturated esters were obtained in satisfactory to good yields with the complete retention of the nitro group. (C) 2009 Elsevier Ltd. All rights reserved.File in questo prodotto:
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