At room temperature, one equivalent of primary haloalkane and aldehyde, or conjugated enone, in the presence of IRA-402 nitrite and Amberlyst A-21, gave (beta-nitroalkanols or gamma-nitro ketones, respectively, via a one-pot tandem S(N)2-nitroaldol (Henry) or S(N)2-Michael reactions
A New Heterogeneous One-Pot Process for Both Nitroaldol (Henry) and Michael Reactions from Primary Haloalkanes via Nitroalkanes
BALLINI, Roberto;BARBONI, Luciano;PALMIERI, Alessandro
2007-01-01
Abstract
At room temperature, one equivalent of primary haloalkane and aldehyde, or conjugated enone, in the presence of IRA-402 nitrite and Amberlyst A-21, gave (beta-nitroalkanols or gamma-nitro ketones, respectively, via a one-pot tandem S(N)2-nitroaldol (Henry) or S(N)2-Michael reactionsFile in questo prodotto:
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