Several aliphatic nitro compounds have been employed as stabilized carbanions in the conjugate addition to a variety of electron-poor alkenes (Michael reaction). Depending on the nature of the alkene, new carbon-carbon single or double bonds can be generated. However, all the Michael adducts can be efficiently utilized as key building blocks for the synthesis of a huge array of fine chemicals, including homo- and heterocyclic structures

Synthesis of fine chemicals by the conjugate addition of nitroalkanes to electrophilic alkenes

BALLINI, Roberto;BARBONI, Luciano;BOSICA, Giovanna;FIORINI, Dennis;PALMIERI, Alessandro
2006-01-01

Abstract

Several aliphatic nitro compounds have been employed as stabilized carbanions in the conjugate addition to a variety of electron-poor alkenes (Michael reaction). Depending on the nature of the alkene, new carbon-carbon single or double bonds can be generated. However, all the Michael adducts can be efficiently utilized as key building blocks for the synthesis of a huge array of fine chemicals, including homo- and heterocyclic structures
2006
262
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/113458
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