The chemoselective, conjugate addition of nitroalkanes to electron-poor alkenes, with two electron-withdrawing groups in the alpha- and beta-positions, can be easily performed at room temperature under solventless conditions using potassium fluoride/basic alumina as heterogeneous catalyst.
Potassium fluoride/basic alumina as far superior heterogeneous catalyst for the chemoselective conjugate addition of nitroalkanes to electron-poor alkenes having two electron-withdrawing groups in alpha- and beta-positions
BALLINI, Roberto;PALMIERI, Alessandro
2006-01-01
Abstract
The chemoselective, conjugate addition of nitroalkanes to electron-poor alkenes, with two electron-withdrawing groups in the alpha- and beta-positions, can be easily performed at room temperature under solventless conditions using potassium fluoride/basic alumina as heterogeneous catalyst.File in questo prodotto:
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