The reaction of primary 1,3-dinitroalkanes with 2-ene-1,4-dione or 2-ene-4-oxo ester derivatives in acetonitrile with DBU as base, allow the one pot synthesis of 3,5-alkylated acetophenones and methyl benzoate derivatives respectively via an anionic domino process.
One-Pot Synthesis of 3,5-Alkylated Acetophenone and Methyl Benzoate Derivatives via Anionic Domino Process
BALLINI, Roberto;BARBONI, Luciano;FIORINI, Dennis;GIARLO, Guido;PALMIERI, Alessandro
2005-01-01
Abstract
The reaction of primary 1,3-dinitroalkanes with 2-ene-1,4-dione or 2-ene-4-oxo ester derivatives in acetonitrile with DBU as base, allow the one pot synthesis of 3,5-alkylated acetophenones and methyl benzoate derivatives respectively via an anionic domino process.File in questo prodotto:
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