One pot, many reactions! The reaction of two equivalents of ethyl(2-bromomethyl)acrylate with dinitroalkanes (see scheme) leads to the one-pot, diastereoselective synthesis of a variety of polyfunctionalized bicyclo[3.3.1]nonanes in very good overall yields. The reaction proceeds through an anionic domino process, with the in situ generation of four new C-C bonds
Diastereoselective One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process.
BARBONI, Luciano;GABRIELLI, Serena;PALMIERI, Alessandro;BALLINI, Roberto
2009-01-01
Abstract
One pot, many reactions! The reaction of two equivalents of ethyl(2-bromomethyl)acrylate with dinitroalkanes (see scheme) leads to the one-pot, diastereoselective synthesis of a variety of polyfunctionalized bicyclo[3.3.1]nonanes in very good overall yields. The reaction proceeds through an anionic domino process, with the in situ generation of four new C-C bondsFile in questo prodotto:
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