One pot, many reactions! The reaction of two equivalents of ethyl(2-bromomethyl)acrylate with dinitroalkanes (see scheme) leads to the one-pot, diastereoselective synthesis of a variety of polyfunctionalized bicyclo[3.3.1]nonanes in very good overall yields. The reaction proceeds through an anionic domino process, with the in situ generation of four new C-C bonds

Diastereoselective One-Pot Synthesis of Polyfunctionalized Bicyclo[3.3.1]nonanes by an Anionic Domino Process.

BARBONI, Luciano;GABRIELLI, Serena;PALMIERI, Alessandro;BALLINI, Roberto
2009-01-01

Abstract

One pot, many reactions! The reaction of two equivalents of ethyl(2-bromomethyl)acrylate with dinitroalkanes (see scheme) leads to the one-pot, diastereoselective synthesis of a variety of polyfunctionalized bicyclo[3.3.1]nonanes in very good overall yields. The reaction proceeds through an anionic domino process, with the in situ generation of four new C-C bonds
2009
262
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/112283
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 14
  • ???jsp.display-item.citation.isi??? 13
social impact