Synthesis, characterization of some diorganotin(IV) complexes of Schiff bases derived from a non-protein amino acid. Crystal structures of {HO2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p} and its di-n-butyltin(IV) complex (nBu2Sn{O2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p}2)

BASU BAUL, T; Masharinga, C; Basu, S; Pettinari, Claudio; Rivarola, E; Chantraprommad, S; Fun, H. K.

doi:10.1002/aoc.1358

CAMPUS è l'Archivio istituzionale delle pubblicazioni scientifiche dell’Università di Camerino. E’ un sistema aperto, pubblico e interoperabile che raccoglie, conserva ed espone i dati relativi alle attività e ai prodotti della ricerca dell’Ateneo con lo scopo di migliorarne la visibilità e di favorirne l’impatto a livello nazionale e internazionale.

Diorganotin(IV) complexes R2Sn(LH)2 (R = Me, nBu) and {[nBu2Sn(LH)]2O}2 (LH = 4-[(2Z)-(3-hydroxy-1-methyl-2- butenylidene)amino]benzoate and 4-[{(E)-1-(2-hydroxyphenyl)methylidene}mino]benzoate) have been reported. The complexes were characterized by elemental analysis, IR, NMR (1H, 13C, 119Sn) and 119mSn M¨ ossbauer spectroscopy. Crystal structures of a ligand {HO2CC6H4[N C(H)}{C(CH3)CH(CH3)-3-OH]-p} and one of its di-n-butyltin(IV) complexes (nBu2Sn{O2CC6H4[N C(H)}{C(CH3)CH(CH3)-3-OH]-p}2) were determined. The spectroscopic data suggest that R2Sn(LH)2 complexes have skew-trapezoidal bipyramidal structure while {[nBu2Sn(LH)]2O}2 complexes adopt a dimeric tetraorganodistannoxane structure in the solid state and undergo complex exchange processes in deuterochloroform solution, as revealed by 119Sn NMR spectroscopy.

Scheda prodotto non validato

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Titolo:	Synthesis, characterization of some diorganotin(IV) complexes of Schiff bases derived from a non-protein amino acid. Crystal structures of {HO2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p} and its di-n-butyltin(IV) complex (nBu2Sn{O2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p}2)
Autori:	BASU BAUL T MASHARINGA C BASU S PETTINARI, Claudio RIVAROLA E CHANTRAPROMMAD S FUN H. K. mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2008
Rivista:	APPLIED ORGANOMETALLIC CHEMISTRY
Citazione:	Synthesis, characterization of some diorganotin(IV) complexes of Schiff bases derived from a non-protein amino acid. Crystal structures of {HO2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p} and its di-n-butyltin(IV) complex (nBu2Sn{O2CC6H4[N=C(H){C(CH3)CH(CH3)-3-OH]-p}2) / BASU BAUL T; MASHARINGA C; BASU S; C. PETTINARI; RIVAROLA E; CHANTRAPROMMAD S; FUN H.-K. - In: APPLIED ORGANOMETALLIC CHEMISTRY. - ISSN 0268-2605. - 22:2(2008), pp. 114-121.
Abstract:	Diorganotin(IV) complexes R2Sn(LH)2 (R = Me, nBu) and {[nBu2Sn(LH)]2O}2 (LH = 4-[(2Z)-(3-hydroxy-1-methyl-2- butenylidene)amino]benzoate and 4-[{(E)-1-(2-hydroxyphenyl)methylidene}mino]benzoate) have been reported. The complexes were characterized by elemental analysis, IR, NMR (1H, 13C, 119Sn) and 119mSn M¨ ossbauer spectroscopy. Crystal structures of a ligand {HO2CC6H4[N C(H)}{C(CH3)CH(CH3)-3-OH]-p} and one of its di-n-butyltin(IV) complexes (nBu2Sn{O2CC6H4[N C(H)}{C(CH3)CH(CH3)-3-OH]-p}2) were determined. The spectroscopic data suggest that R2Sn(LH)2 complexes have skew-trapezoidal bipyramidal structure while {[nBu2Sn(LH)]2O}2 complexes adopt a dimeric tetraorganodistannoxane structure in the solid state and undergo complex exchange processes in deuterochloroform solution, as revealed by 119Sn NMR spectroscopy.
Handle:	http://hdl.handle.net/11581/107625
Appare nelle tipologie:	Articolo

File in questo prodotto:

Non ci sono file associati a questo prodotto.

Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11581/107625

Citazioni

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.