It has been found that commercial ISOLUTER Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and c-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.

Isosolute Si-carbonate Catalyzes the Nitronate Addition of both Aldehydes and Electron-poor Alkenes under Solvent-Free Conditions

BALLINI, Roberto;BOSICA, Giovanna;PALMIERI, Alessandro;
2008-01-01

Abstract

It has been found that commercial ISOLUTER Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and c-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.
2008
262
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11581/103980
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact