It has been found that commercial ISOLUTER Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and c-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.
Isosolute Si-carbonate Catalyzes the Nitronate Addition of both Aldehydes and Electron-poor Alkenes under Solvent-Free Conditions
BALLINI, Roberto;BOSICA, Giovanna;PALMIERI, Alessandro;
2008-01-01
Abstract
It has been found that commercial ISOLUTER Si-carbonate catalyzes both nitroaldol and Michael reactions, from nitroalkanes and under solvent-free conditions, allowing satisfactory to good yields of nitroalkanols and c-nitro-functionalized carbonyl and cyano derivatives. In addition, a one-pot Henry–Michael reaction can be performed.File in questo prodotto:
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