Over the past decades, half-sandwich Ir(III), Rh(III), and Ru(II) complexes have received considerable attention due to their potential applications. This chapter will address historical background and recent developments on the coordination chemistry of half-sandwich derivatives of (arene)Ru(II), CpRu(II), CpRh(III) and CpIr(III) (Cp = cyclopentadienyl) with pyrazoles and pyrazole-based ligands and their potential applications. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.

Half-Sandwich Rhodium(III), Iridium(III), and Ruthenium(II) Complexes with Ancillary Pyrazole-Based Ligands

PETTINARI, Claudio;PETTINARI, Riccardo;DI NICOLA, CORRADO;MARCHETTI, Fabio
2013

Abstract

Over the past decades, half-sandwich Ir(III), Rh(III), and Ru(II) complexes have received considerable attention due to their potential applications. This chapter will address historical background and recent developments on the coordination chemistry of half-sandwich derivatives of (arene)Ru(II), CpRu(II), CpRh(III) and CpIr(III) (Cp = cyclopentadienyl) with pyrazoles and pyrazole-based ligands and their potential applications. Synthetic methods and the structural and functional properties of the target complexes are discussed in detail.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11581/290981
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