Rigid tetrahedral ligands are of particular interest in Metal-Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting fluorite or garnet topology with copper(ii), manganese(ii) and cadmium(ii) metal based nodes.
Microporous metal-organic frameworks built from rigid tetrahedral tetrakis(4-tetrazolylphenyl)silane connectors
PETTINARI, Claudio;
2014-01-01
Abstract
Rigid tetrahedral ligands are of particular interest in Metal-Organic Framework (MOF) construction due to their highly branched nature, high symmetry and also their rarity. Within this context the silicon-centred linker tetrakis(4-tetrazolylphenyl)silane is shown to give porous networks exhibiting fluorite or garnet topology with copper(ii), manganese(ii) and cadmium(ii) metal based nodes.File in questo prodotto:
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