2-Nitrocycloalkanones are smoothly converted into dicarboxylic acids or ketoacids, depending on whether the nitro group is secondary or tertiary, by treatment with aqueous 30% hydrogen peroxide and potassium carbonate in methyl alcohol solution for 8-10h at room temperature.
A New Oxidative Cleavage of 2-Nitrocycloalkanones by Hydrogen Peroxide: An important, Efficient Method for Dicarboxylic Acid or Ketoacid Synthesis
BALLINI, Roberto;MARCANTONI, Enrico;PETRINI, Marino;
1988-01-01
Abstract
2-Nitrocycloalkanones are smoothly converted into dicarboxylic acids or ketoacids, depending on whether the nitro group is secondary or tertiary, by treatment with aqueous 30% hydrogen peroxide and potassium carbonate in methyl alcohol solution for 8-10h at room temperature.File in questo prodotto:
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